1-(3,3-Diethoxyprop-1-yn-1-yl)-3-methylbenzene → 3-(m-Tolyl)propiolaldehyde

HRID 2040887Notes

Reaction equation

HRID 2040887 reaction equation
ClC1C=C(C#CC=O)C=CC=1.C([O:14][CH:15](OCC)[C:16]#[C:17][C:18]1[CH:23]=[CH:22][CH:21]=[C:20]([CH3:24])[CH:19]=1)C>>[CH3:24][C:20]1[CH:19]=[C:18]([C:17]#[C:16][CH:15]=[O:14])[CH:23]=[CH:22][CH:21]=1

Participants

3

Reactant 2

HCID 107988731-(3,3-Diethoxyprop-1-yn-1-yl)-3-methylbenzeneHCID 468725403-(3-Chlorophenyl)-2-propynal

Product 1

HCID 107731013-(m-Tolyl)propiolaldehyde

Procedure

The title compound was synthesized following the procedure reported for Compound 31d, but starting from Compound 91a instead of Compound 31c. The crude title compound was used in the next step without further purification.

Workup

  1. customThe crude title compound was used in the next step without further purification

Sources & evidence

ORD record
ord-0ac243aaa1b841659bffd022b0fab313
Source dataset
uspto-grants-2013_11
Patent number
US08580962B2

Reaction notes

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