Isobutyryl chloride → HCID 68475981, compound

HRID 2041859Notes

Reaction equation

HRID 2041859 reaction equation
[CH:1]1[C:14]2[CH2:13][C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[S:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[C:15](Cl)(=[O:19])[CH:16]([CH3:18])[CH3:17].[Cl-].[Al+3].[Cl-].[Cl-]>>[C:15]([C:10]1[CH:9]=[CH:8][C:7]2[S:6][C:5]3[C:14](=[CH:1][C:2]([C:15](=[O:19])[CH:16]([CH3:18])[CH3:17])=[CH:3][CH:4]=3)[CH2:13][C:12]=2[CH:11]=1)(=[O:19])[CH:16]([CH3:18])[CH3:17]

Participants

4

Reactant 3

HCID 62325Isobutyryl chlorideHCID 67495ThioxantheneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 68475981HCID 68475981, compound

Procedure

A reaction as described in example 1b by using thioxanthene, isobutyryl chloride, and aluminium chloride gives the product. The structure is confirmed by Mass [M=366] and the 1H-NMR spectrum (CDCl3). δ[ppm]: 0.99 (d, 12H), 2.29 (hept, 2H), 2.82 (d, 4H), 4.00 (s, 2H), 7.50 (d, 2H), 7.79 (d, 2H), 7.92 (s, 2H).

Workup

  1. customA reaction
  2. customgives the product

Sources & evidence

ORD record
ord-5c76565900eb4080a867dad6d56f4559
Source dataset
uspto-grants-2013_11
Patent number
US08586268B2

Reaction notes

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