HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexane → HCID 66995406, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexane | HCID 8058 | — |
| Reactant | 1,3-Dichloroacetone | HCID 10793 | — |
| Reactant | 1-Bromo-3-chloro-5-fluorobenzene | HCID 2736223 | — |
| Reactant | HCID 178506865 | HCID 178506865 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 66995406 | HCID 66995406 | — |
Reaction Steps
Preparation according to Preparation 1: 1-bromo-3-chloro-5-fluorobenzene (5 g, 23.9 mmol), dry diethyl ether (100 mL), n-hexyllithium in hexane (2.3 M, 10.4 ml, 23.9 mmol) and 1,3-dichloroacetone (3.03 g, 23.9 mol). Yield: 4.49 g (73%). MS m/z (rel. intensity, 70 eV) 257 (M+, 1), 209 (65), 207 (bp), 211 (11), 143 (28).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08586572B2 |
| Source dataset | uspto-grants-2013_11 |
| ORD ID | ord-db22914065034fc2a5da2891d9064260 |
| Source note | uspto-grants-2013_11 |