HCID 53897072, compound → 4-Hydroxy-1-iodo trans-1-octene

HRID 2049261Notes

Reaction equation

HRID 2049261 reaction equation
[I:1][CH:2]=[CH:3][CH2:4][CH:5]([O:10][Si](C)(C)C)[CH2:6][CH2:7][CH2:8][CH3:9]>C(O)(=O)C.O1CCCC1.O>[OH:10][CH:5]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:4]/[CH:3]=[CH:2]/[I:1]

Participants

5

Reactant 1

HCID 53897072HCID 53897072, compound

Product 1

HCID 128512784-Hydroxy-1-iodo trans-1-octene

Reagents, catalysts & solvents 3

HCID 176Acetic AcidSolventHCID 962WaterSolventHCID 8028TetrahydrofuranSolvent

Procedure

A 23 g portion of 1-iodo-4-trimethylsilyloxy-1-octene is dissolved in a mixture of 200 ml of glacial acetic acid, 100 ml of tetrahydrofuran, and 50 ml of water. Concentration provides the named product.

Workup

  1. concentrationConcentration
  2. customprovides the named product

Sources & evidence

ORD record
ord-173c027a948140c9938f7511dfff9d33
Source dataset
uspto-grants-1980_04
Patent number
US04197245

Reaction notes

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