HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pyridine → HCID 86736925, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | Hydroxylamine HCl | HCID 21645 | — |
| Reactant | HCID 12796452 | HCID 12796452 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 86736925 | HCID 86736925 | — |
Reaction Steps
A mixture of 5α-pregna-2,16-diene-11,20-dione (60 g), hydroxylammonium chloride (21 g) and anhydrous pyridine (240 ml) was left to stand at room temperature overnight before diluting with ice and water. The precipitate obtained was collected by filtration, washed with water and dried in vacuo at 80° (62 g.). Crystallisation from ethyl acetate afforded the title compound, m.p. 168°-182°, [α]D +137°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04197296 |
| Source dataset | uspto-grants-1980_04 |
| ORD ID | ord-6eae89936aac4bd7b6152ead60e521b3 |
| Source note | uspto-grants-1980_04 |