Thiocyanic acid, chloromethyl ester → HCID 53789278, compound

HRID 2049672Notes

Reaction equation

HRID 2049672 reaction equation
[CH3:1][C:2]1[CH:3]=[C:4]([CH:8]=[CH:9][CH:10]=1)[C:5]([OH:7])=[S:6].Cl[CH2:12][S:13][C:14]#[N:15]>>[S:13]([CH2:12][O:7][C:5](=[S:6])[C:4]1[CH:8]=[CH:9][CH:10]=[C:2]([CH3:1])[CH:3]=1)[C:14]#[N:15]

Participants

3

Reactant 2

HCID 76755Thiocyanic acid, chloromethyl esterHCID 178425328HCID 178425328, compound

Product 1

HCID 53789278HCID 53789278, compoundYield 79%

Procedure

10 g (0.052 mol) of the K salt of 3-methyl-thiobenzoic acid and 5.6 g (0.05 mol) of chloromethyl thiocyanate were reacted and processed as in Example 1 B. 9.9 g of an oily liquid having a density of 1.27 (this corresponds to a yield of 79% of the theoretical conversion).

Sources & evidence

ORD record
ord-a01231965cc34d65b3b6c7c3d89a4463
Source dataset
uspto-grants-1980_04
Patent number
US04198428

Reaction notes

Loading…