3-(4-Chlorophenoxy)2-methyl-1-propene → HCID 20344578, compound

HRID 2049817Notes

Reaction equation

HRID 2049817 reaction equation
[Cl:1][C:2]1[CH:12]=[CH:11][C:5]([O:6][CH2:7][C:8]([CH3:10])=[CH2:9])=[CH:4][CH:3]=1.CC(C)([O-])C.[K+]>O>[Cl:1][C:2]1[CH:12]=[CH:11][C:5]([O:6][CH:7]=[C:8]([CH3:9])[CH3:10])=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 124099273-(4-Chlorophenoxy)2-methyl-1-propeneHCID 23665647Potassium tert-butoxide

Product 1

HCID 20344578HCID 20344578, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Seven grams of 3-(4-chlorophenoxy)2-methyl-1-propene and 0.35 g of potassium t-butoxide are heated at 150° under nitrogen for 3 days. The mixture is then worked up with water and extracted with ether. The organic phase is washed with dilute acid, water and brine, dried over magnesium sulfate and solvent is removed to yield 3-(4-chlorophenoxy)-2-methyl-2-propene.

Workup

  1. extractionextracted with ether
  2. washThe organic phase is washed
  3. additionwith dilute acid, water and brine
  4. dry with materialdried over magnesium sulfate and solvent
  5. customis removed

Sources & evidence

ORD record
ord-ec1071bd5aba40378722c6f082f079d4
Source dataset
uspto-grants-1980_04
Patent number
US04198527

Reaction notes

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