Water → Acetamide, N-(4,5,6,7-tetrahydro-7-oxobenzo[b]thien-4-yl)-

HRID 2049923Notes

Reaction equation

HRID 2049923 reaction equation
[S:1]1[CH:5]=[CH:4][C:3]2[CH:6]([NH:10][C:11](=[O:13])[CH3:12])[CH2:7][CH2:8][CH2:9][C:2]1=2.[OH2:14]>>[O:14]=[C:9]1[C:2]2[S:1][CH:5]=[CH:4][C:3]=2[CH:6]([NH:10][C:11](=[O:13])[CH3:12])[CH2:7][CH2:8]1

Participants

3

Reactant 2

HCID 962WaterHCID 4976773N-(4,5,6,7-Tetrahydrobenzo[b]thiophen-4-yl)acetamide

Product 1

HCID 106675Acetamide, N-(4,5,6,7-tetrahydro-7-oxobenzo[b]thien-4-yl)-

Conditions

Temperature
60 °C

Procedure

Into a 100 ml, three necked round bottomed flask is placed 2.0 g of N-(4,5,6,7-tetrahydrobenz[b]-thien-4-yl)acetamide, 15 ml of H2O, and 31.5 ml of a 1.3 M cobaltic acetate solution prepared as in Example II. The mixture is stirred and heated to 60° C. under N2 for 12 hours and is worked up as in Example V. A material weighing 1.9 g and assaying as 76.8% of the product was obtained.

Workup

  1. customwas obtained

Sources & evidence

ORD record
ord-61a2f91be9414315b69759e95661976e
Source dataset
uspto-grants-1980_04
Patent number
US04199510

Reaction notes

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