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HRID2050397

反应详情

EQUATION

反应方程式

HRID 2050397 的结构方程式

REACTANTS

反应物

5
结构：Cc1ccc(S(=O)(=O)O)cc1
HCID6101

4-Methylbenzenesulfonic acid

C7H8O3S

结构：[N-]=[N+]=[N-].[Na+]
HCID33557

未命名化合物

结构：[BH4-].[Na+]
HCID4311764

Sodium borohydride (Na(BH4))

H4BNa

结构：OCC1CCN1
HCID15251628

(Azetidin-2-yl)methanol

C4H9NO

结构：COC(=O)[C@@H]1NC(=O)[C@@H]1n1c(-c2ccccc2)c(-c2ccccc2)oc1=O
HCID70577957

未命名化合物

PRODUCTS

生成物

1
结构：[N-]=[N+]=NC[C@@H]1NC(=O)[C@@H]1n1c(-c2ccccc2)c(-c2ccccc2)oc1=O
HCID86736960

未命名化合物

PROCEDURE

实验过程

Sodium borohydride reduction of methyl cis-3-(4,5-diphenyl-2-oxo-4-oxazolin-3-yl)-4-oxoazetidine-2-carboxylate as described in Preparation 3, followed by conversion of the 2-hydroxymethylazetidine product to the p-toluenesulfonate derivative and reaction of this derivative with sodium azide as described in Preparation 4 gives the title compound.

WORKUP

后处理

  1. customas described in Preparation 4