HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Alcohol → HCID 14230566, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Alcohol | HCID 244 | — |
| Reactant | 4-Methoxybenzyl alcohol | HCID 7738 | — |
| Reactant | Trichloroethanol | HCID 8259 | — |
| Reactant | Borneol | HCID 64685 | — |
| Reactant | HCID 13470812 | HCID 13470812 | — |
| Reactant | Methyl cis-1-(2,4-Dimethoxybenzyl)-3-amino-4-oxoazetidine-2-carboxylate | HCID 18632686 | — |
| Reactant | HCID 70593087 | HCID 70593087 | — |
| Solvent | tert-Butanol | HCID 6386 | — |
| Product | HCID 14230566 | HCID 14230566 | — |
Reaction Steps
When p-methoxybenzyl alcohol, isoborneol, benzyl alcohol or 2,2,2-trichloroethanol is substituted for t-butanol in Preparation 5 in the reaction with methyl cis-3-amino-1-(2,4-dimethoxybenzyl)-4-oxoazetidine-2-carboxylate, methyl cis-1-(2,4-dimethoxybenzyl)-3-(p-methoxybenzyloxycarbonylamino)-4-oxoazetidine-2-carboxylate, methyl cis-1-(2,4-dimethoxybenzyl)-3-isobornyloxycarbonylamino-4-oxoazetidine-2-carboxylate, methyl cis-3-benzyloxycarbonylamino-1-(2,4-dimethoxybenzyl)-4-oxoazetidine-2-carboxylate or methyl cis-1-(2,4-dimethoxybenzyl)-4-oxo-3-(2,2,2-trichloroethoxycarbonylamino)-azetidine-2-carboxylate is obtained, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04200572 |
| Source dataset | uspto-grants-1980_04 |
| ORD ID | ord-ee0ac9e7098444388f66f86f3888e464 |
| Source note | uspto-grants-1980_04 |