HuagongsheHuagongshe Chemistry Print Report · For research reference only
D-Arabinose → Lyxose
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | D-Arabinose | HCID 66308 | — |
| Reactant | Aldehydo-D-ribose | HCID 5311110 | — |
| Solvent | Methanol--water (1/1) | HCID 22242641 | — |
| Product | Lyxose | HCID 65550 | — |
| Product | aldehydo-D-Xylose | HCID 644160 | — |
| Product | Aldehydo-D-ribose | HCID 5311110 | — |
Reaction Steps
By means of this process it is possible for example to epimerize an approximately 35% strength by weight solution of arabinose in 1:1 methanol/water to D-ribose with a conversion of 35% and a ribose selectivity of 91% without forming detectable amounts of D-lyxose or xylose. The sugar loss is only about 3%. The product solution thus obtained has only a slight yellow color. It can be concentrated to a dry substance content of about 70% to crystallize the bulk of the unconverted arabinose in at least 99% purity, which can be recycled into the epimerization.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05015296 |
| Source dataset | uspto-grants-1991_05 |
| ORD ID | ord-360c0bf4032548d69096ceb1f6d8b8b3 |
| Source note | uspto-grants-1991_05 |