HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl iodide → HCID 848831, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | 2-Hydroxy-3,6,7-trimethylquinoxaline | HCID 247489 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 848831 | HCID 848831 | — |
Reaction Steps
A mixture of 3,6,7-trimethyl-2(1H)-quinoxalinone (5.0 g., 0.027 mol.), methyl iodide (15 ml.), sodium carbonate (5.0 g., 0.047 mol.) and dimethylformamide (75 ml.) were stirred at room temperature for eighteen hours, then heated at 75°-80° C. for three hours. Removal of the dimethylformamide under reduced pressure and dilution with water gave a brown solid. Crystallization from acetone (Darco) gave light tan needles. (2.85 g., m.p. 164-166°, 53%)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04181724 |
| Source dataset | uspto-grants-1980_01 |
| ORD ID | ord-1465c3f8220f46f694cf298204098fc2 |
| Source note | uspto-grants-1980_01 |