1,3-Dioxolane → HCID 20378047, compound

HRID 2051746Notes

Reaction equation

HRID 2051746 reaction equation
[O:1]1[CH2:6][CH2:5][CH2:4][O:3][C:2]1([C:12]([O:14]CC)=[O:13])[C:7]([O:9]CC)=[O:8].[OH-].[Na+:18].O1CCOC1>>[O:1]1[CH2:6][CH2:5][CH2:4][O:3][C:2]1([C:7]([O-:9])=[O:8])[C:12]([O-:14])=[O:13].[Na+:18].[Na+:18]

Participants

4

Reactant 3

HCID 125861,3-DioxolaneHCID 14798Sodium HydroxideHCID 20378058HCID 20378058, compound

Product 1

HCID 20378047HCID 20378047, compoundYield 102.6%

Procedure

Hydrolysis of 9.0 g (0.039 mol) of diethyl 1,3-dioxane-2,2-dicarboxylate with 6.8 g of 50% aqueous sodium hydroxide as described in Example 2 for the dioxolane analog yielded 8.4 g (0.04 mol) 98% of the title compound as a white free flowing solid.

Sources & evidence

ORD record
ord-c66742bc8374478fb937acb01e45c935
Source dataset
uspto-grants-1980_01
Patent number
US04182718

Reaction notes

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