HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formic Acid → HCID 20378784, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formic Acid | HCID 284 | — |
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | 2-Methylbenzamide | HCID 10704 | — |
| Reactant | Phosphorus pentachloride | HCID 24819 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 20378784 | HCID 20378784 | — |
Reaction Steps
A mixture containing 48 g (0.36 mole) of 2-methylbenzamide, 74 g (0.36 mole) of phosphorus pentachloride and 500 ml of AR carbon tetrachloride was heated at 60°-70° for 30 min. at which time the HCl gas evolution had ceased. The solution was cooled to 30° and 16.9 g (0.36 mole) of 97% formic acid added dropwise. Stirring was continued following the addition for 40-50 min. The product was colleted, washed with AR carbon tetrachloride and air-dried to give 56 g, m.p. 91°-93°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04182881 |
| Source dataset | uspto-grants-1980_01 |
| ORD ID | ord-223b335de3094566b546b64e35ff7e04 |
| Source note | uspto-grants-1980_01 |