HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formic Acid → HCID 54181364, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formic Acid | HCID 284 | — |
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Phosphorus pentachloride | HCID 24819 | — |
| Reactant | trans-Cinnamamide | HCID 5273472 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 54181364 | HCID 54181364 | — |
Reaction Steps
Heated at 70° for 25 min. at which time the HCl gas evolution had ceased, a mixture of 59 g (0.4 mole) of cinnamide, 83.5 g (0.4 mole) of phosphorus pentachloride and 500 ml of AR carbon tetrachloride. After cooling to 30°, added dropwise, 19 g (0.4 mole) of 97% formic acid. Chilled to 0° and filtered. Air-dried to give 107.5 g, m.p. softens 82°, melts 83°-90°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04182881 |
| Source dataset | uspto-grants-1980_01 |
| ORD ID | ord-719c8a0fba5246908497e413958dd99b |
| Source note | uspto-grants-1980_01 |