Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzylamine → 3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzylamine | HCID 7504 | — |
| 반응물 | cis-1,2-Cyclopropanedicarboxylic acid | HCID 726455 | — |
| 반응물 | 3-Azabicyclo[3.1.0]hexane-2-carboxylic acid | HCID 3779453 | — |
| 반응물 | 3-Azabicyclo[3.1.0]hexane | HCID 13150523 | — |
| 생성물 | 3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione | HCID 2764586 | — |
반응 단계
3-Azabicyclo(3.1.0)hexane, a precursor for preparing 3-azabicyclo(3.1.0)hexane-2-carboxylic acid, a plant gametocide, is prepared by (a) treating cis-1,2-cyclopropanedicarboxylic acid with benzylamine, to form 3-(benzyl)-3-azabicyclo(3.1.0)hexane-2,4-dione, (b) selectively reducing the dione to 3-(benzyl)-3-azabicyclo(3.1.0)hexane, and (c) hydrogenolysis of that compound to 3-azabicyclo(3.1.0)hexane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04183857 |
| 출처 데이터셋 | uspto-grants-1980_01 |
| ORD ID | ord-a78236e8d59740808417ec75df9d4b6f |
| 출처 메모 | uspto-grants-1980_01 |