2,6-Dimethylaniline → Benzenamine, N-(2-methoxyethyl)-2,6-dimethyl-

HRID 2052230Notes

Reaction equation

HRID 2052230 reaction equation
[CH3:1][C:2]1[CH:8]=[CH:7][CH:6]=[C:5]([CH3:9])[C:3]=1[NH2:4].[H][H].[CH3:12][O:13][CH2:14][CH2:15]O>>[CH3:1][C:2]1[CH:8]=[CH:7][CH:6]=[C:5]([CH3:9])[C:3]=1[NH:4][CH2:15][CH2:14][O:13][CH3:12]

Participants

4

Reactant 3

HCID 68962,6-DimethylanilineHCID 80192-MethoxyethanolHCID 178418361HCID 178418361, compound

Product 1

HCID 170858Benzenamine, N-(2-methoxyethyl)-2,6-dimethyl-

Conditions

Temperature
275 °C

Procedure

In a quartz tube 30 cm in length and 0.5 cm in diameter, which is arranged vertically and surrounded by a heating jacket, 2 ml of this catalyst are activated at 130° C., in the manner described in Example 2, and then heated to 275° C. under hydrogen. At 275° C., 1.21 g of 2,6-dimethylaniline, 1.52 g of 2-methoxyethanol and 0.67 N1 of hydrogen are then passed, per hour, under normal pressure, through the reactor from top to bottom. The mixture which issues from the reactor is condensed and worked up by distillation.

Workup

  1. customIn a quartz tube 30 cm in length and 0.5 cm in diameter, which is arranged vertically
  2. customare activated at 130° C., in the manner
  3. customcondensed
  4. distillationworked up by distillation

Sources & evidence

ORD record
ord-2a4e8b84365a4d5ea713710eb2ff1f94
Source dataset
uspto-grants-1980_01
Patent number
US04183868

Reaction notes

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