Ammonium Hydroxide → HCID 20377835, compound

HRID 2052379Notes

Reaction equation

HRID 2052379 reaction equation
[OH:1][C:2]1[C:3](=O)[CH:4]=[CH:5][C:6]([N:9]=[O:10])=[CH:7][CH:8]=1.[OH-].[NH4+:13]>>[NH2:13][C:3]1[C:2](=[O:1])[CH:8]=[CH:7][C:6]([N:9]=[O:10])=[CH:5][CH:4]=1

Participants

3

Reactant 2

HCID 14923Ammonium HydroxideHCID 168072,4,6-CYCLOHEPTATRIENE-1-ONE, 2-HYDROXY-5-NITROS

Product 1

HCID 20377835HCID 20377835, compound

Procedure

Conc. ammonium hydroxide solution (50 ml) is added dropwise to a suspension of 2-hydroxy-5-nitroso-2,4,6-cycloheptatrien-1-one [10 g, described by T. Nozoe et al., Sci. Repts. Tohoku Univ., 35, 274- 82 (1952), (CA 47 3291a)] collected and washed with water then acetone to give 2-amino-5-nitroso-2,4,6-cycloheptatrien-1-one.

Workup

  1. customcollected
  2. washwashed with water

Sources & evidence

ORD record
ord-6d73edb128be4e118270a9d41fa068c3
Source dataset
uspto-grants-1980_01
Patent number
US04183955

Reaction notes

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