Hydrochloric Acid → HCID 23452782, compound

HRID 2052609Notes

Reaction equation

HRID 2052609 reaction equation
[CH2:1]([C:5]1(O)[C:10]([CH3:12])(C)[CH2:9][C:8](=[O:13])[CH:7]=[C:6]1[CH3:14])[CH2:2][CH2:3][CH3:4].Cl.[C:17]1(=O)C=CCC=C1>CCCCCC>[CH2:1]([C:5]1([CH3:17])[C:6]([CH3:14])=[CH:7][C:8](=[O:13])[CH:9]=[C:10]1[CH3:12])[CH2:2][CH2:3][CH3:4]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 1385582,5-CyclohexadienoneHCID 147596004-Butyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one

Product 1

HCID 23452782HCID 23452782, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A solution of 7 g of 4-butyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one (prepared by the procedure of Example IV) in hexane is stirred overnight with 10 ml of a 5% solution of HCl. The hexane is separated and evaporated, and the residue is distilled through a micro column using triethanolamine as a still base. The product obtained is 4-butyl-3,4,5-trimethyl-(2,5-cyclohexadien-1-one, boiling point 112°-119° C. at 0.1 mm Hg. The compound exhibits the following spectral characteristics:

Workup

  1. customThe hexane is separated
  2. customevaporated
  3. distillationthe residue is distilled through a micro column
  4. customThe product obtained

Sources & evidence

ORD record
ord-3803d517a6ae41ca900784ad02d69493
Source dataset
uspto-grants-1980_01
Patent number
US04186149

Reaction notes

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