HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azanylidyneoxidanium → Phenol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azanylidyneoxidanium | HCID 84878 | — |
| Reactant | Cumen hydroperoxide | HCID 53627471 | — |
| Product | Phenol | HCID 996 | — |
| Product | Alpha-Methylstyrene | HCID 7407 | — |
| Product | Acetophenone | HCID 7410 | — |
| Product | 2-Phenyl-2-propanol | HCID 12053 | — |
Reaction Steps
In this example 0.01 g. (455 ppm.) of nitrosonium hexachlorostibnate was added to the cumene hydroperoxide. The temperature rose to a maximum temperature of 90° C. and after five minutes the products were removed for analysis. The reaction resulted in a selectivity of 84 percent to phenol, 13 percent to alpha-methylstyrene, 3 percent to acetophenone and one percent to dimethylbenzyl alcohol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04210607 |
| Source dataset | uspto-grants-1980_07 |
| ORD ID | ord-c01b5d1a262e4310a9af530f0269440c |
| Source note | uspto-grants-1980_07 |