m-Chloroperbenzoic acid → 3-Chlorobenzoic Acid
Reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([C:8]([O:10]O)=[O:9])[CH:3]=1>O>[Cl:1][C:2]1[CH:3]=[C:4]([CH:5]=[CH:6][CH:7]=1)[C:8]([OH:10])=[O:9]Participants
3
Reactant 1
Product 1
Reagents, catalysts & solvents 1
Procedure
The compound (e1) (54 mg) and m-chloroperbenzoic acid (23.4 mg) were stirred together in water (2 ml). After 10 minutes the m-chlorobenzoic acid that had formed was filtered off, the pH was adjusted to 7 by the addition of a small amount of dilute sodium bicarbonate solution and the water was then removed by evaporation on a rotary evaporator to yield the compound (e2) as a solid (60%).
Sources & evidence
- ORD record
- ord-5f254311602d450aadc6f51088687fe7
- Source dataset
- uspto-grants-1980_07
- Patent number
- US04210662
Reaction notes
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