HCID 20331375, compound → HCID 20331378, compound

HRID 2057588Notes

Reaction equation

HRID 2057588 reaction equation
[C:1]([C:4]1[C:5]([OH:18])=[CH:6][C:7]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][C:8]=2[C:14]=1[CH2:15][CH:16]=[CH2:17])(=[O:3])[CH3:2]>C(O)C.[Pd]>[C:1]([C:4]1[C:5]([OH:18])=[CH:6][C:7]2[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][C:8]=2[C:14]=1[CH2:15][CH2:16][CH3:17])(=[O:3])[CH3:2]

Participants

4

Reactant 1

HCID 20331375HCID 20331375, compound

Product 1

HCID 20331378HCID 20331378, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

The product from step (b) (12 gm) was dissolved in ethanol (150 ml) and reduced with 5% palladium on carbon (1.2 gm) under an atmosphere of hydrogen (45 psi). The catalyst was removed by filtration and the ethanol was removed in vacuo to yield the product as a brown mobile oil. Wt 11.5 gm.

Workup

  1. customThe catalyst was removed by filtration
  2. customthe ethanol was removed in vacuo

Sources & evidence

ORD record
ord-2c85362625e944acbb065d8a61b74807
Source dataset
uspto-grants-1980_07
Patent number
US04211788

Reaction notes

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