Ammonia → HCID 20331562, compound

HRID 2057623Notes

Reaction equation

HRID 2057623 reaction equation
[CH:1]1[C:13]2[CH:12]([N:14]=[C:15]=[S:16])[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[NH3:17]>CCOCC>[CH:1]1[C:13]2[CH:12]([NH:14][C:15]([NH2:17])=[S:16])[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 222AmmoniaHCID 14714141HCID 14714141, compound

Product 1

HCID 20331562HCID 20331562, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To 16.52 g (0.074 mole) of 9-fluorenylisothiocyanate in ether is added excess anhydrous NH3 with cooling. The reaction mixture is capped and allowed to stand overnight at 0° C. Filtration gives the product, N-(9-fluorenyl)-thiourea, m.p. (158°) 182°-189° C.

Workup

  1. temperaturewith cooling
  2. customThe reaction mixture is capped
  3. filtrationFiltration

Sources & evidence

ORD record
ord-bb34f21c353749e0bd68c1513e3fe4b9
Source dataset
uspto-grants-1980_07
Patent number
US04211867

Reaction notes

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