HuagongsheHuagongshe Chemistry Print Report · For research reference only
Toluene → HCID 20331197, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Toluene | HCID 1140 | — |
| Reactant | 2,4-Dinitrobenzenesulfonic acid | HCID 6959 | — |
| Reactant | Ethyl 3-(4-aminophenyl)propanoate | HCID 10442595 | — |
| Reactant | 5-Octylthiophene-2-carbaldehyde | HCID 13791588 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 20331197 | HCID 20331197 | — |
Reaction Steps
A solution of 8.6 g. ethyl 4-aminohydrocinnamate, 9.77 g. 5-octyl-2-thiophenecarboxaldehyde and a few crystals of 2,4-dinitrobenzenesulfonic acid in 250 ml. toluene is refluxed under a Dean-Stark trap for 17 hours, whereupon the theoretical amount (0.8 ml.) water has been collected. The toluene is evaporated to yield ethyl 3-[4-(5-octyl-2-thienylideneamino)phenyl]propionate as a crystalline mass.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04211783 |
| Source dataset | uspto-grants-1980_07 |
| ORD ID | ord-c73f04170c5c4264ae011e01ea7dfbd7 |
| Source note | uspto-grants-1980_07 |