HRID2057795

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID944

Nitric Acid

HNO3

HCID14923

Ammonium hydroxide

H5NO

结构：N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo]

HCID25488

未命名化合物

结构：O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Bi+3]

HCID107711

Bismuth nitrate

BiN3O9

结构：N.N.N.N.N.N.O.O.O.O.[O]=[Mo](=[O])([OH])[OH].[O]=[Mo](=[O])([OH])[OH].[O]=[Mo](=[O])([OH])[OH].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O].[O]=[Mo](=[O])=[O]

HCID16211167

未命名化合物

PRODUCTS

生成物

结构：[Bi+3].[Bi+3].[Mo].[Mo].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2]

HCID159680

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

PROCEDURE

实验过程

10.91 g Bi(NO3)3.5H2O was dissolved in about 40 ml. of a 10% aqueous HNO3 solution. 5.96 g of (NH4)6Mo7O24.4H2O was dissolved in about 75 ml. of H2O with heating. The bismuth nitrate solution was added with constant stirring to the ammonium heptamolybdate solution. The pH of the mixture was then adjusted to 2.5 to 3 by the dropwise addition of reagent grade NH4OH. The mixture was then stirred for 1 hour to produce a bismuth molybdate slurry.