Methyl Isocyanate → HCID 54329214, compound

HRID 2058151Notes

Reaction equation

HRID 2058151 reaction equation
[CH3:1][C:2]([CH3:13])([CH3:12])[C:3](=[N:10][OH:11])[CH:4]([S:7]([CH3:9])=[O:8])[S:5][CH3:6].[CH3:14][N:15]=[C:16]=[O:17]>C(Cl)Cl>[CH3:14][NH:15][C:16]([O:11][N:10]=[C:3]([C:2]([CH3:13])([CH3:12])[CH3:1])[CH:4]([S:7]([CH3:9])=[O:8])[S:5][CH3:6])=[O:17]

Participants

4

Reactant 2

HCID 12228Methyl IsocyanateHCID 86737114HCID 86737114, compound

Product 1

HCID 54329214HCID 54329214, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

To 50 mg of 3,3-dimethyl-1-(methylsulfinyl)-1-methylthio-2-butanone oxime in 5 ml of methylene chloride is added 0.5 ml of methyl isocyanate. After standing at room temperature 18 hrs., the solvent was removed to give 53 mg of impure 3,3-dimethyl-1-(methylsulfinyl)-1-methylthio-2-butanone O-[methylaminocarbonyl]oxime. The ir and pmr were identical to that of an authentic sample synthesized independently.

Workup

  1. custom, the solvent was removed

Sources & evidence

ORD record
ord-7b099a16137e40698c1355050db92162
Source dataset
uspto-grants-1980_07
Patent number
US04215075

Reaction notes

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