4-Chlorophenol → 1-Chloro-4-(1,1,2,2-tetrafluoroethoxy)benzene

HRID 2058278Notes

Reaction equation

HRID 2058278 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.[F:9][C:10]([F:14])=[C:11]([F:13])[F:12]>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][C:11]([F:13])([F:12])[CH:10]([F:14])[F:9])=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 46844-ChlorophenolHCID 8301Tetrafluoroethylene

Product 1

HCID 127807041-Chloro-4-(1,1,2,2-tetrafluoroethoxy)benzene

Procedure

4-Chlorophenol reacts under basic catalysis with tetrafluoroethylene to give 1-chloro-4-(1,1,2,2-tetrafluoroethoxy)benzene as a colorless oil of b.p. 68° at 12 Torr. [For example, see J. Am Chem. Soc. 73, 5831 (1951) and Chem. Abstr. 73, 36584q.]

Sources & evidence

ORD record
ord-09275a936c9d4db7b4336720c0afd33a
Source dataset
uspto-grants-1980_07
Patent number
US04215145

Reaction notes

Loading…