HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Acetylthiophene → 4-Fluorononan-5-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Acetylthiophene | HCID 6920 | — |
| Reactant | 5-Nonanone | HCID 10405 | — |
| Reactant | 18-Pentatriacontanone | HCID 10440 | — |
| Reactant | Chlorotriethylsilane | HCID 13819 | — |
| Reactant | Hypofluorous acid, trifluoromethyl ester | HCID 78989 | — |
| Product | 4-Fluorononan-5-one | HCID 13447109 | — |
Reaction Steps
Similarly, 2-acetylthiophene, 5-nonanone and stearone give, for example, by treatment with chlorotriethylsilane, the corresponding siloxy compounds which, upon reaction with trifluoromethyl hypofluorite, give 2-β-fluoroacetylthiophene, 4-fluorononane-5-one and α-fluorostearone, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04215044 |
| Source dataset | uspto-grants-1980_07 |
| ORD ID | ord-cc0a803cbc3f46eb93cc99f6ee7825b6 |
| Source note | uspto-grants-1980_07 |