2-Acetylthiophene → HCID 13447109, compound

HRID 2058297Notes

Reaction equation

HRID 2058297 reaction equation
C(C1SC=CC=1)(=O)C.[CH3:9][CH2:10][CH2:11][CH2:12][C:13](=[O:18])[CH2:14][CH2:15][CH2:16][CH3:17].CCCCCCCCCCCCCCCCCC(CCCCCCCCCCCCCCCCC)=O.Cl[Si](CC)(CC)CC.[F:63]OC(F)(F)F>>[F:63][CH:12]([C:13](=[O:18])[CH2:14][CH2:15][CH2:16][CH3:17])[CH2:11][CH2:10][CH3:9]

Participants

6

Reactant 5

HCID 69202-AcetylthiopheneHCID 104055-NonanoneHCID 1044018-PentatriacontanoneHCID 13819ChlorotriethylsilaneHCID 78989Hypofluorous acid, trifluoromethyl ester

Product 1

HCID 13447109HCID 13447109, compound

Procedure

Similarly, 2-acetylthiophene, 5-nonanone and stearone give, for example, by treatment with chlorotriethylsilane, the corresponding siloxy compounds which, upon reaction with trifluoromethyl hypofluorite, give 2-β-fluoroacetylthiophene, 4-fluorononane-5-one and α-fluorostearone, respectively.

Sources & evidence

ORD record
ord-cc0a803cbc3f46eb93cc99f6ee7825b6
Source dataset
uspto-grants-1980_07
Patent number
US04215044

Reaction notes

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