HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,12-Dodecanediamine → HCID 86738277, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,12-Dodecanediamine | HCID 17727 | — |
| Reactant | N-{2-[({5-[(Dimethylamino)methyl]furan-2-yl}methyl)sulfanyl]ethyl}-1-(methylsulfanyl)-2-nitroethen-1-amine | HCID 53427435 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 86738277 | HCID 86738277 | 77.1% |
Reaction Steps
A mixture of N,N-dimethyl-5-[[[2-[(1-methylthio-2-nitroethenyl)amino]ethyl]thio]methyl]-2-furanmethanamine (2 g) and 1,12-diaminododecane (0.6 g) was heated at 100° for 3 hours. The oily residue was chromatographed (silica/methanol-0.88 ammonia, 79:1) to give an oil which solidified on trituration with ether giving the title compound (1.77 g) mp. 74°-76°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04317819 |
| Source dataset | uspto-grants-1982_03 |
| ORD ID | ord-532d49ff8f434af2911555d03c032d96 |
| Source note | uspto-grants-1982_03 |