1,12-Dodecanediamine → HCID 86738277, compound

HRID 2058420Notes

Reaction equation

HRID 2058420 reaction equation
[CH3:1][N:2]([CH3:21])[CH2:3][C:4]1[O:5][C:6]([CH2:9][S:10][CH2:11][CH2:12][NH:13][C:14](SC)=[CH:15][N+:16]([O-:18])=[O:17])=[CH:7][CH:8]=1.[NH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][NH2:35]>CCOCC>[CH3:21][N:2]([CH2:3][C:4]1[O:5][C:6]([CH2:9][S:10][CH2:11][CH2:12][NH:13][C:14]([NH:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][NH:35][C:14]([NH:13][CH2:12][CH2:11][S:10][CH2:9][C:6]2[O:5][C:4]([CH2:3][N:2]([CH3:1])[CH3:21])=[CH:8][CH:7]=2)=[CH:15][N+:16]([O-:18])=[O:17])=[CH:15][N+:16]([O-:18])=[O:17])=[CH:7][CH:8]=1)[CH3:1]

Participants

4

Reactant 2

HCID 177271,12-DodecanediamineHCID 53427435N-{2-[({5-[(Dimethylamino)methyl]furan-2-yl}methyl)sulfanyl]ethyl}-1-(methylsulfanyl)-2-nitroethen-1-amine

Product 1

HCID 86738277HCID 86738277, compoundYield 77.1%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

A mixture of N,N-dimethyl-5-[[[2-[(1-methylthio-2-nitroethenyl)amino]ethyl]thio]methyl]-2-furanmethanamine (2 g) and 1,12-diaminododecane (0.6 g) was heated at 100° for 3 hours. The oily residue was chromatographed (silica/methanol-0.88 ammonia, 79:1) to give an oil which solidified on trituration with ether giving the title compound (1.77 g) mp. 74°-76°.

Workup

  1. temperaturewas heated at 100° for 3 hours
  2. customThe oily residue was chromatographed (silica/methanol-0.88 ammonia, 79:1)
  3. customto give an oil which

Sources & evidence

ORD record
ord-532d49ff8f434af2911555d03c032d96
Source dataset
uspto-grants-1982_03
Patent number
US04317819

Reaction notes

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