Benzylaniline → HCID 13037507, compound

HRID 2058907Notes

Reaction equation

HRID 2058907 reaction equation
[CH2:1]([NH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:15][O:16][C:17]1[CH:22]=[CH:21][C:20]([P:23](Cl)(Cl)=[O:24])=[CH:19][CH:18]=1>>[CH3:15][O:16][C:17]1[CH:22]=[CH:21][C:20]([P:23]2(=[O:24])[C:3]3[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=3[CH2:1][N:8]2[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:19][CH:18]=1

Participants

3

Reactant 2

HCID 66028BenzylanilineHCID 216711Phosphonic dichloride, (p-methoxyphenyl)-

Product 1

HCID 13037507HCID 13037507, compoundYield 7%

Procedure

The procedure of Example 26 was employed utilizing N-benzylaniline and 4-methoxyphenyl phosphonic dichloride to yield 1-(4-methoxyphenyl)-2-phenyl-2,3-dihydro-1H-2,1-benzazaphosphole-1-oxide (0.7 g, 7% yield) as a white solid having a melting point of 190°-192° C. and the following analysis:

Sources & evidence

ORD record
ord-25ebc9b8bd5b4b909ada084517fb828b
Source dataset
uspto-grants-1982_03
Patent number
US04319913

Reaction notes

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