HRID2059095

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11776

Triphenylphosphine

C18H15P

HCID6093376

未命名化合物

PRODUCTS

生成物

结构：[Cl][Ru][Cl].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1

HCID11007548

Dichlorotris(triphenylphosphine)ruthenium

C54H45Cl2P3Ru

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

CONDITIONS

反应条件

温度: 75 °C

PROCEDURE

实验过程

To a 100 cc glass flask is added 50 mls. of methanol, 5.0 grams of triphenylphosphine and 1.0 gram of ruthenium trichloride hydrate. The resulting mixture is stirred and heated by means of an oil bath under an atmosphere of nitrogen to a temperature of 75° C. and maintained at that temperature for 6 hours. Tris(triphenylphosphine) ruthenium dichloride is formed as a brown insoluble powder, which is recovered by filtration (3.9 gram).

WORKUP

后处理

additionTo a 100 cc glass flask is added 50 mls
temperaturemaintained at that temperature for 6 hours

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f7ae3c9a9b8348b29a965d654f91a6e9
来源数据集: uspto-grants-1982_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04321414
来源说明: uspto-grants-1982_03

反应 SMILES

[C:1]1([P:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.O.[Ru:21](Cl)([Cl:23])[Cl:22]>CO>[Ru:21]([Cl:23])[Cl:22].[C:14]1([P:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1.[C:14]1([P:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1.[C:14]1([P:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1