HRID2059096

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID13956

Phosphine, tris(4-methylphenyl)-

C21H21P

HCID6093376

未命名化合物

PRODUCTS

生成物

结构：Cc1ccc(P(c2ccc(C)cc2)c2ccc(C)cc2)cc1.Cc1ccc(P(c2ccc(C)cc2)c2ccc(C)cc2)cc1.Cc1ccc(P(c2ccc(C)cc2)c2ccc(C)cc2)cc1.[Cl][Ru][Cl]

HCID10855191

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

Using the procedure of Example 1, 50 mls. of methanol, 6.0 grams of tri-paratolylphosphine and 1.0 gram of ruthenium trichloride hydrate are stirred and heated at reflux under nitrogen for 24 hours to form tris(tri-paratolylphosphine) ruthenium dichloride as an insoluble powder which is recovered by filtration (4.2 grams).

WORKUP

后处理

temperatureheated
temperatureat reflux under nitrogen for 24 hours

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-a37b42f07d0f45a8b752e9bb879d634d
来源数据集: uspto-grants-1982_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04321414
来源说明: uspto-grants-1982_03

反应 SMILES

[C:1]1([CH3:22])[CH:6]=[CH:5][C:4]([P:7]([C:15]2[CH:20]=[CH:19][C:18]([CH3:21])=[CH:17][CH:16]=2)[C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.O.[Ru:24](Cl)([Cl:26])[Cl:25]>CO>[Ru:24]([Cl:26])[Cl:25].[C:18]1([CH3:21])[CH:19]=[CH:20][C:15]([P:7]([C:8]2[CH:9]=[CH:10][C:11]([CH3:14])=[CH:12][CH:13]=2)[C:4]2[CH:5]=[CH:6][C:1]([CH3:22])=[CH:2][CH:3]=2)=[CH:16][CH:17]=1.[C:18]1([CH3:21])[CH:19]=[CH:20][C:15]([P:7]([C:8]2[CH:9]=[CH:10][C:11]([CH3:14])=[CH:12][CH:13]=2)[C:4]2[CH:5]=[CH:6][C:1]([CH3:22])=[CH:2][CH:3]=2)=[CH:16][CH:17]=1.[C:18]1([CH3:21])[CH:19]=[CH:20][C:15]([P:7]([C:8]2[CH:9]=[CH:10][C:11]([CH3:14])=[CH:12][CH:13]=2)[C:4]2[CH:5]=[CH:6][C:1]([CH3:22])=[CH:2][CH:3]=2)=[CH:16][CH:17]=1