HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Cyclohexanedione → 2-[(Dimethylamino)methylidene]cyclohexane-1,3-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Cyclohexanedione | HCID 10434 | — |
| Reactant | Dimethylformamide dimethyl acetal | HCID 78373 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 2-[(Dimethylamino)methylidene]cyclohexane-1,3-dione | HCID 359353 | — |
Reaction Steps
A MeCN solution of cyclohexane-1,3-dione 2.24 g (0.02 mol) i and DMF-DMA 11.9 g (0.1 mol) was stirred at room temperature for 4 h. The solvent was removed under reduced pressure and the product was used for the next step with no purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08288400B2 |
| Source dataset | uspto-grants-2012_10 |
| ORD ID | ord-6bc954deaddd45a7a48765e933f4900b |
| Source note | uspto-grants-2012_10 |