2-Cyclohexen-1-one, 4,4-dimethyl- → Cyclohexanone, 4,4-dimethyl-

HRID 2063941Notes

Reaction equation

HRID 2063941 reaction equation
[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][C:5](=[O:8])[CH:4]=[CH:3]1.[H][H]>[Pd].CCCCC>[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][C:5](=[O:8])[CH2:4][CH2:3]1

Participants

5

Reactant 2

HCID 1368392-Cyclohexen-1-one, 4,4-dimethyl-HCID 178418361HCID 178418361, compound3×

Product 1

HCID 138166Cyclohexanone, 4,4-dimethyl-Yield 98.3%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8003PentaneSolvent

Procedure

4,4-dimethyl-cyclohexen-1-one (5 g, 40.3 mmol) were placed in a hydrogen reaction vessel and n-pentane (15 ml) was added, and Pd/C (500 mg) was added thereto. The hydrogen reaction vessel was pressurized with hydrogen (25 psi), and the reaction was conducted for 30 minutes. After completing the reaction, the solid like material was filtered through Celite and the filtrate was concentrated in vacuo to give the title compound (5 g, 98%).

Workup

  1. additionwas added
  2. customthe reaction
  3. filtrationthe solid like material was filtered through Celite
  4. concentrationthe filtrate was concentrated in vacuo

Sources & evidence

ORD record
ord-c6344220aefc4d849e2e87e48db8996d
Source dataset
uspto-grants-2012_10
Patent number
US08288386B2

Reaction notes

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