Methyl Benzoate → Benzoate

HRID 2068472Notes

Reaction equation

HRID 2068472 reaction equation
[C:1]([O:9]C)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:11]([OH:16])[CH2:12][CH2:13][CH2:14][OH:15].C(O)C[O:19]CCO>>[C:14]([O:15][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)(=[O:19])[CH3:13].[C:1]([O-:9])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:11]([OH:16])[CH2:12][CH2:13][CH2:14][OH:15]

Participants

6

Reactant 3

HCID 7150Methyl BenzoateHCID 80641,4-Butanediol2×HCID 8117Diethylene Glycol

Product 3

HCID 242BenzoateHCID 80641,4-ButanediolHCID 31229Phenyl acetate

Procedure

In the same manner as in Example 1-11 except for using 120 g of methyl phenyl acetate, 55 g of methyl benzoate and 36 g of 1,4-butandiol in place of 180 g of methyl phenyl acetate and 43 g of diethylene glycol, 80 g of a mixture of phenylacetic acid diester of 1,4-butandiol (48%), a phenyl acetate and benzoate of 1,4-butandiol (42 mass %), and benzoic acid diester of 1,4-butandiol (10 mass %) was obtained.

Sources & evidence

ORD record
ord-e705d92c769a43b29e368c44121e92f2
Source dataset
uspto-grants-2012_10
Patent number
US08299004B2

Reaction notes

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