HCID 12794151, compound → HCID 178506822, compound

HRID 2071413Notes

Reaction equation

HRID 2071413 reaction equation
[C:1]1([C:7]2[N:8]=[C:9]3[C:14](=[C:15]4[C:20]=2[CH2:19][CH2:18][CH2:17][CH2:16]4)[CH2:13][CH2:12][CH2:11][CH2:10]3)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([Li:25])CCC>>[Li:25][CH:10]1[C:9]2[C:14](=[C:15]3[C:20](=[C:7]([C:1]4[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=4)[N:8]=2)[CH2:19][CH2:18][CH2:17][CH2:16]3)[CH2:13][CH2:12][CH2:11]1

Participants

3

Reactant 2

HCID 12794151HCID 12794151, compoundHCID 178418339Butyllithium

Product 1

HCID 178506822HCID 178506822, compound

Procedure

By the method of Example 2, 1,2,3,4,7,8,9,10-octahydro-6-phenyl-phenanthridine is reacted with n-butyl-lithium solution to give 1,2,3,4,7,8,9,10-octahydro-4-lithio-6-phenylphenanthridine which in turn is reacted with trimethylsilyl isothiocyanate to give 1,2,3,4,7,8,9,10-octahydro-6-phenylphenanthridine-4-thiocarboxamide.

Sources & evidence

ORD record
ord-c0fd7d00835d4eb89385b596e4113139
Source dataset
uspto-grants-1977_09
Patent number
US04046895

Reaction notes

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