4-Toluenesulfonyl chloride → HCID 21413950, compound

HRID 2071436Notes

Reaction equation

HRID 2071436 reaction equation
[CH2:1]([O:3][CH:4]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH2:5][OH:6])[CH3:2].[C:21]1([CH3:31])[CH:26]=[CH:25][C:24]([S:27](Cl)(=[O:29])=[O:28])=[CH:23][CH:22]=1>N1C=CC=CC=1>[C:21]1([CH3:31])[CH:26]=[CH:25][C:24]([S:27]([O:6][CH2:5][CH:4]([O:3][CH2:1][CH3:2])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:29])=[O:28])=[CH:23][CH:22]=1

Participants

4

Reactant 2

HCID 73974-Toluenesulfonyl chlorideHCID 202079332-Ethoxyhexadecan-1-ol

Product 1

HCID 21413950HCID 21413950, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

2-Ethoxyhexadecyl p-toluenesulfonate was prepared by treating 2-ethoxyhexadecanol (1.72 g) with p-toluenesulfonylchloride (1.5 g) in pyridine (2.3 ml) at room temperature over night. There was obtained 2.47 g of a crude product, which by thin layer chromatography was shown to contain very small amounts of impurities.

Sources & evidence

ORD record
ord-425a602eeee14d86bd0b70fc918be5b9
Source dataset
uspto-grants-1977_09
Patent number
US04046914

Reaction notes

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