HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2071614Generated: November 1, 2026
Ethylene Glycol → Bis(2-hydroxyethyl) terephthalate
https://huagongshe.com/reaction/2071614
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ethylene Glycol | HCID 174 | — |
| Reactant | Methanol | HCID 887 | — |
| Reactant | Dimethyl terephthalate | HCID 8441 | — |
| Catalyst | Manganous Acetate | HCID 12525 | — |
| Product | Bis(2-hydroxyethyl) terephthalate | HCID 13739 | — |
Reaction Steps
12 Parts by weight of dimethylterephthalate, 8 parts by weight of ethylene-glycol and 0.025 % of the brightener compound No. 201 (cf. Table shown above) were melted under a nitrogen atmosphere in a stainless stell vessel provided with a stirring device, at a temperature of from 140° to 150° C. After the melt had reached a temperature of 145° C, it was mixed with 0.02 parts of manganese acetate dissolved in one part of glycol. In a temperature range of from 160° to 220° C, the transesterification was carried out within 3 hours under atmospheric pressure, in which process methanol and, towards the end, part of the glycol were distilled off. The bis-(β-hydroxyethyl)-terephthalate obtained was brought to a temperature of 240° C in a condensation vessel made of stainless steel, after 1 part by weight of ethylene-glycol had been added, together with
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04048185 |
|---|
| Source dataset | uspto-grants-1977_09 |
|---|
| ORD ID | ord-d96b4c924ede4f4c82e286039a6dc2bc |
|---|
| Source note | uspto-grants-1977_09 |
|---|