Back
HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2071614Generated: November 1, 2026

Ethylene Glycol → Bis(2-hydroxyethyl) terephthalate

https://huagongshe.com/reaction/2071614

Reaction equation

Participants

RoleNameHCIDCharge
ReactantEthylene GlycolHCID 174—
ReactantMethanolHCID 887—
ReactantDimethyl terephthalateHCID 8441—
CatalystManganous AcetateHCID 12525—
ProductBis(2-hydroxyethyl) terephthalateHCID 13739—

Reaction Steps

12 Parts by weight of dimethylterephthalate, 8 parts by weight of ethylene-glycol and 0.025 % of the brightener compound No. 201 (cf. Table shown above) were melted under a nitrogen atmosphere in a stainless stell vessel provided with a stirring device, at a temperature of from 140° to 150° C. After the melt had reached a temperature of 145° C, it was mixed with 0.02 parts of manganese acetate dissolved in one part of glycol. In a temperature range of from 160° to 220° C, the transesterification was carried out within 3 hours under atmospheric pressure, in which process methanol and, towards the end, part of the glycol were distilled off. The bis-(β-hydroxyethyl)-terephthalate obtained was brought to a temperature of 240° C in a condensation vessel made of stainless steel, after 1 part by weight of ethylene-glycol had been added, together with

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04048185
Source datasetuspto-grants-1977_09
ORD IDord-d96b4c924ede4f4c82e286039a6dc2bc
Source noteuspto-grants-1977_09