HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl chloride → Propane, 2-bromo-1-chloro-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl chloride | HCID 7850 | — |
| Reactant | 1-Bromo-3-chloropropane | HCID 8006 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | 1-Bromo-3-chloropropane | HCID 8006 | — |
| Product | Propane, 2-bromo-1-chloro- | HCID 18175 | 3% |
Reaction Steps
The same process as in example 2 was carried out, but the cyclohexane was replaced by 3-bromo-1-chloropropane. The reaction developed in the same way. After 30 minutes of irradiation at 22° C, 90% of allyl chloride had been converted. The reaction product was degassed and the unreacted allyl chloride was distilled. The remaining product was formed by 3-bromo-1-chloropropane (solvent + formed product) and about 3% of 2-bromo-1-chloropropane. This operation has the advantage of making the solvent distillation unnecessary.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04049516 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-fd729aa701f2427aaa34fce67080442c |
| Source note | uspto-grants-1977_09 |