m-Chloroperbenzoic acid → Pyridine, 2-[[(3,4-dimethylphenyl)methyl]sulfinyl]-, 1-oxide

HRID 2072258Notes

Reaction equation

HRID 2072258 reaction equation
[CH3:1][C:2]1[CH:3]=[C:4]([CH2:9][S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])[CH:5]=[CH:6][C:7]=1[CH3:8].C1C=C(Cl)C=C(C(OO)=[O:26])C=1>C(Cl)(Cl)Cl>[CH3:1][C:2]1[CH:3]=[C:4]([CH2:9][S:10]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])=[O:26])[CH:5]=[CH:6][C:7]=1[CH3:8]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 54496084HCID 54496084, compound

Product 1

HCID 501078Pyridine, 2-[[(3,4-dimethylphenyl)methyl]sulfinyl]-, 1-oxide

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical to that of Example 68 using 7.4 gm (0.03 mol) 2-(3,4-dimethylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform with 6 gm (0.03 mol) MCPBA (85%) in 100 ml chloroform.

Sources & evidence

ORD record
ord-ba41d155d7764a219bc823c56637dce6
Source dataset
uspto-grants-1977_09
Patent number
US04050921

Reaction notes

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