m-Chloroperbenzoic acid → HCID 53708244, compound

HRID 2072259Notes

Reaction equation

HRID 2072259 reaction equation
[O:1]=[C:2]([C:12]1[CH:17]=[C:16]([CH3:18])[CH:15]=[CH:14][C:13]=1[CH3:19])[CH2:3][S:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][N+:6]=1[O-:11].C1C=C(Cl)C=C(C(OO)=[O:28])C=1>C(Cl)(Cl)Cl>[O:1]=[C:2]([C:12]1[CH:17]=[C:16]([CH3:18])[CH:15]=[CH:14][C:13]=1[CH3:19])[CH2:3][S:4]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][N+:6]=1[O-:11])=[O:28]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 54362319HCID 54362319, compound

Product 1

HCID 53708244HCID 53708244, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical to that of Example 68 using 8.2 gm (0.03 mol) 2-(2-oxo-2-[2,5-dimethylphenyl]ethylthio)pyridine N-oxide in 50 ml chloroform with 6 gm (0.03 mol) MCPBA (85%) in 100 ml chloroform.

Sources & evidence

ORD record
ord-d116ff8544664b53908a1f6f1faf82ce
Source dataset
uspto-grants-1977_09
Patent number
US04050921

Reaction notes

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