m-Chloroperbenzoic acid → Pyridine, 2-[[(4-methoxyphenyl)methyl]sulfinyl]-, 1-oxide

HRID 2072262Notes

Reaction equation

HRID 2072262 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([CH2:9][S:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])=[CH:5][CH:4]=1.C1C=C(Cl)C=C(C(OO)=[O:26])C=1>C(Cl)(Cl)Cl>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([CH2:9][S:10]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][N+:12]=2[O-:17])=[O:26])=[CH:5][CH:4]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 54179610HCID 54179610, compound

Product 1

HCID 501087Pyridine, 2-[[(4-methoxyphenyl)methyl]sulfinyl]-, 1-oxide

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

The procedure employed is identical to that of Example 68 using 7 gm (0.028 mol) 2-(4-methoxyphenylmethylthio)pyridine N-oxide in 50 ml of chloroform and 5.6 gm (0.028 mol) MCPBA in 100 ml chloroform.

Sources & evidence

ORD record
ord-59b08c298b1e41bfab705ee8341d3d19
Source dataset
uspto-grants-1977_09
Patent number
US04050921

Reaction notes

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