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HRID2072399

反应详情

EQUATION

反应方程式

HRID 2072399 的结构方程式

REACTANTS

反应物

3
结构：c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID11776

Triphenylphosphine

C18H15P

结构：[PH4+]
HCID5460504

Phosphonium

H4P+

结构：CCOC(=O)c1ccccc1CBr
HCID11032082

Ethyl 2-(bromomethyl)benzoate

C10H11BrO2

PRODUCTS

生成物

1
结构：CCOC(=O)c1ccccc1C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]
HCID19092713

{[2-(Ethoxycarbonyl)phenyl]methyl}(triphenyl)phosphanium bromide

C28H26BrO2P

AUXILIARIES

试剂、催化剂与溶剂

1
结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

PROCEDURE

实验过程

20 g of the ester described under (1) above are mixed with a solution of 28 g of triphenyl phosphine in 250 ml of benzene, and the mixture is heated to boiling for about 290 hours. The precipitated phosphonium salt is sucked off and dried.

WORKUP

后处理

  1. temperaturethe mixture is heated
  2. customdried