HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Dioxide → HCID 54373755, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | 6-chloro-1H-indazol-3-amine | HCID 85628 | — |
| Solvent | Diethyl Pyrocarbonate | HCID 3051 | — |
| Product | HCID 54373755 | HCID 54373755 | — |
Reaction Steps
0.3 mol of 3-amino-6-chloroindazole in 250 ml of pyrocarbonic acid diethyl ester are heated, while stirring, to 50° C for about 5 hours, until the evolution of CO2 has ceased. After cooling, 250 ml of diethyl ether are added and 90% of theory of 3-amino-6-chloroindazole-2-carboxylic acid ethyl ester are isolated, by filtration, in the form of yellow crystals. Melting point: 163°-165° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04051252 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-bc913b5f65574c3baacfe4421d93939e |
| Source note | uspto-grants-1977_09 |