HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzene → HCID 21409291, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzene | HCID 241 | — |
| Reactant | Chloroform | HCID 6212 | — |
| Reactant | Aminomatacil | HCID 25072 | — |
| Reactant | 2-Chloropropionyl chloride | HCID 111019 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | HCID 21409291 | HCID 21409291 | 95.7% |
Reaction Steps
Utilizing benzene and chloroform as the solvent and triethylamine as the acid acceptor, 3-methyl-4-aminophenyl N-methylcarbamate (2.5g., 0.0139 mole) was reacted with α-chloropropionyl chloride (1.79g., 0.0141 mole) to yield the desired product as a white powder (3.6g.). Recrystallization from ethanol/water to give material with m.p. 167°-70° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04051254 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-0c82a491c74243f594d6042cec90b4b8 |
| Source note | uspto-grants-1977_09 |