Thiophenol → HCID 54165568, compound

HRID 2072708Notes

Reaction equation

HRID 2072708 reaction equation
Br[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9](=[CH:14][O:15][CH3:16])[C:10]([O:12][CH3:13])=[O:11].[C:17]1([SH:23])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1.C(=O)([O-])[O-].[K+].[K+]>>[C:17]1([S:23][CH2:2][C:3]2[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=2[C:9](=[CH:14][O:15][CH3:16])[C:10]([O:12][CH3:13])=[O:11])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1

Participants

4

Reactant 3

HCID 7969ThiophenolHCID 11430Potassium CarbonateHCID 53395349Methyl 2-[2-(bromomethyl)phenyl]-3-methoxyprop-2-enoate

Product 1

HCID 54165568HCID 54165568, compoundYield 97%

Procedure

2 g of methyl α-(2-bromomethylphenyl)-β-methoxyacrylate, 0.65 g of thiophenol and 1.1 g of potassium carbonate are reacted similarly to Example 1. 1.8 g of white crystals of melting point 71° C. are obtained (compound No. 2).

Sources & evidence

ORD record
ord-c5e47136744d46ebbc6cb5afae453ade
Source dataset
uspto-grants-1990_04
Patent number
US04914128

Reaction notes

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