Acetone → HCID 51136438, compound

HRID 2073148Notes

Reaction equation

HRID 2073148 reaction equation
[C:1](#N)[CH:2]=C.OCCO[C:9](=[O:12])[CH:10]=[CH2:11].S[CH:14](O)C.CC(N=N[C:24]([C:27]#N)([CH3:26])C)(C#N)C.[CH3:29][C:30]([CH3:32])=[O:31]>>[CH3:29][C:30]1([OH:31])[CH:11]2[CH2:1][CH2:2][C:9]([OH:12])([CH3:14])[CH:10]2[CH:26]=[CH:24][CH2:27][CH2:32]1

Participants

6

Reactant 5

HCID 180AcetoneHCID 6547AzobisisobutyronitrileHCID 7855AcrylonitrileHCID 131652-Hydroxyethyl acrylateHCID 4713212Mercapto-ethanol

Product 1

HCID 51136438HCID 51136438, compound

Procedure

In a manner analogous to that described hereinabove, an NPBA (BA-4) is prepared by polymerizing 53.06 g (1.0 mole) acrylonitrile and 23.22 g (0.2 mole) hydroxyethylacrylate, in the presence of 3.9 g of mercaptoethanol with AIBN (3.0 g) in 125 ml acetone at 60° C. for 6 hr. The GPC peak mol wt, determined as above, is 28,000 and the OH equivalent weight is 330.

Sources & evidence

ORD record
ord-b31da2b374ce435aba412a62519f4bb9
Source dataset
uspto-grants-1990_04
Patent number
US04915755

Reaction notes

Loading…