4-Cumylphenol → HCID 58415402, compound

HRID 2075214Notes

Reaction equation

HRID 2075214 reaction equation
[CH3:1][C:2]([C:10]1[CH:15]=[CH:14][C:13]([OH:16])=[CH:12][CH:11]=1)([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)[CH3:3].Br[CH2:18][CH:19]([O:23][CH2:24][CH3:25])[O:20][CH2:21][CH3:22]>>[CH2:21]([O:20][CH:19]([O:23][CH2:24][CH3:25])[CH2:18][O:16][C:13]1[CH:12]=[CH:11][C:10]([C:2]([C:4]2[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=2)([CH3:1])[CH3:3])=[CH:15][CH:14]=1)[CH3:22]

Participants

3

Reactant 2

HCID 117424-CumylphenolHCID 74852Ethane, 2-bromo-1,1-diethoxy-

Product 1

HCID 58415402HCID 58415402, compound

Procedure

Synthesized according to Scheme 1, Step 1 from (4-(2-phenylisopropyl)phenol) and 2-bromo-1,1-diethoxyethane to give 1-(2,2-diethoxyethoxy)-4-(2-phenylpropan-2-yl)benzene as a yellow-orange oil. 1H NMR (400 MHz, CHLOROFORM-d) δ ppm 7.19-7.29 (m, 4H), 7.14-7.19 (m, 1H), 7.13 (d, J=9.0 Hz, 2H), 6.82 (d, J=8.5 Hz, 2H), 4.82 (t, J=5.3 Hz, 1H), 3.98 (d, J=5.0 Hz, 2H), 3.70-3.81 (m, 2H), 3.57-3.68 (m, 2H), 1.65 (s, 6H), 1.24 (t, J=7.0 Hz, 6H).

Workup

  1. customSynthesized

Sources & evidence

ORD record
ord-027ecebeaafd47eca3d880de7cec105f
Source dataset
uspto-grants-2011_04
Patent number
US07919519B2

Reaction notes

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